| 摘要: |
| β-甘露糖苷键广泛存在于天然糖复合物中，但选择性地合成β-甘露糖苷键却非常困难；介绍了通过不同的混合缩酮和混合缩醛连接臂介导的分子内糖苷配体转移法(IAD)在选择性地合成β-甘露糖苷键中的应用，同时也讨论了不同连接臂的优势与不足。 |
| 关键词: 分子内糖苷配体转移法 1，2-顺式糖苷键 β-甘露糖苷键 |
| DOI： |
| 分类号: |
| 基金项目: |
|
| Application of Intramolecular Aglycon Delivery to the Synthesis of -Mannosidic Linkage |
|
LI Yi-xue, SUN Bin
|
| Abstract: |
| -mannosidic linkage is widely existed in natural glycans, but selective synthesis of -mannosidic linkage is difficult. This paper mainly introduces the application of intramolecular aglycon delivery (IAD) by connecting hand mediated method via different mixed acetal and mixed ketal to selective synthesis of -mannosidic linkage, and meanwhile discusses the advantages and disadvantages of different connecting hands. |
| Key words: intramolecular aglycon delivery 1,2-cis-glycoside linkage -mannosidic linkage |
