In resent years, China gradually promotes peasants’ citizenization. Because of the huge number of peasants entering into cities and the insufficient urban resources, how to realize the citizenization of most peasants entering into the cities at relatively low cost is the problem for us to solve at present stage. Based on the path analysis of peasants’ citizenization in the process of global urbanization, by associating current reality of China, the interactive mechanism of peasants’ right valueadded transformation by taking employment as core under the synergy between governments and market is put forward and two paths for bigger than zero net earnings after peasants’ citizenization are designed.