微纳双尺度结构形状记忆表面的疏水亲油表面润湿性调控
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Regulation of Hydrophobic and Oleophilic Surface Wettability on Shape Memory Surfaces with Micro-Nano DualScale Structures
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    摘要:

    超疏水亲油表面对水介质呈现疏水性可以实现自清洁和减阻效果,而且对油介质呈现亲油性,针对超疏水 亲油表面对油和水接触角不同的情况,可以达到油水分离,提高对油的利用率。 目的 使微纳结构阵列表面达到疏 水甚至超疏水性,同时还对油滴呈现亲油性,以及利用微纳结构阵列表面在被破坏的情况下的恢复能力,来提高微 纳结构阵列表面的使用寿命。 方法 利用化学腐蚀法与模具法,提出了一种微纳结构阵列形状记忆表面的制备方 法,制备出一种热致型形状记忆聚合物表面。 结果 实验表明:微纳结构阵列形状记忆表面表现为疏水亲油性。 结 论 发现热致型形状记忆聚合物表面因增加微纳结构可以达到超疏水,不同微纳结构表面所表面出来的疏水性不 同,而且可以通过改变温度来实现微纳结构的破坏与恢复的可逆转变,从而实现亲水性和疏水性的转化,同时微纳 结构阵列形状记忆表面具有良好的耐久性。 建立微纳结构阵列形状记忆表面的仿真模型进行润湿模拟,通过实验 与仿真结合的方式计算出所制备表面各个阶段中每个表面的接触角度数,仿真与实验数据的吻合提高数据的可 信度。

    Abstract:

    The superhydrophobic oleophilic surface exhibits hydrophobicity towards aqueous media which can achieve self-cleaning and drag reduction effects. Moreover it exhibits oleophilicity towards oil media. In view of the different contact angles of superhydrophobic and oleophilic surfaces with oil and water oil-water separation can be achieved and the utilization rate of oil can be improved. Objective This study aims to achieve hydrophobic or even superhydrophobic properties while maintaining oleophilicity to oil droplets on micro-nano structured array surfaces and to extend the service life of such surfaces by leveraging their recovery capability after damage. Methods A preparation method for a micro-nano structured array shape memory surface was proposed by using the chemical corrosion method and the mold method and a thermally-induced shape memory polymer surface was prepared. Results Experiments demonstrated that the prepared micro-nano structured shape memory surface exhibited hydrophobicity and lipophilicity. Conclusion The thermallyinduced shape memory polymer surface can achieve superhydrophobicity by adding micro-nano structures. Different micronano structured surfaces show different degrees of hydrophobicity. Moreover the reversible transformation of the destruction and recovery of micro-nano structures can be realized by changing the temperature thus achieving the transformation between hydrophilicity and hydrophobicity. At the same time the micro-nano structured array shape memory surface has good durability. A simulation model of the micro-nano structured array shape memory surface was established for wetting simulation. The contact angles of each surface at various stages of the prepared surface were calculated by combining experiments and simulations. The agreement between simulation and experimental data enhances the credibility of the data.

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左玉辉 ,卢 艳.微纳双尺度结构形状记忆表面的疏水亲油表面润湿性调控[J].重庆工商大学学报(自然科学版),2026,43(4):158-168
ZUO Yuhui LU Yan . Regulation of Hydrophobic and Oleophilic Surface Wettability on Shape Memory Surfaces with Micro-Nano DualScale Structures[J]. Journal of Chongqing Technology and Business University(Natural Science Edition),2026,43(4):158-168

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  • 在线发布日期: 2026-07-07
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