Fe2+ ions produced at Fe anode migrated under direct electric field into the Crcontaminated soil from a chromium slag site in Chongqing to reduce the Cr(VI) in the soil. Experimental results show that Fe2+ produced at anode entered into the soil and migrated from the anode to the cathode. The Fe concentrations in soil increased significantly compared with the initial values, while Cr(Ⅵ) and Cr(Ⅲ) concentrations were lower than their initial values. In the course of the experiment, the emergence of precipitation in the soil near anode significantly affected the uniform distribution of Cr(Ⅵ) removal.