| 引用本文: | 魏星跃,何爱华,王延涛,刘敏,陈正春.新型二异羟肟酸配合物催化PNPP水解的动力学研究(J/M/D/N,J:杂志，M：书，D：论文，N：报纸).期刊名称,2007，（4）： |
| CHEN X. Adap tive slidingmode contr ol for discrete2ti me multi2inputmulti2 out put systems[ J ]. Aut omatica, 2006, 42(6): 4272-435 |
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| 摘要: |
| 以3种含中心功能基(-OCH3)的二异羟肟酸开链冠醚过渡金属铜(Ⅱ)、锌(Ⅱ)和钴(Ⅱ)配合物作为水解酶模型,催化羧酸酯(PNPP)水解;研究了水解反应的动力学和机理,提出了水解反应的动力学模型。结果表明:在室温25℃条件下,这类配合物催化PNPP水解速率随着缓冲溶液pH值的增大而提高,表现出高的催化活性。 |
| 关键词: 中心功能基 异羟肟酸 PNPP水解 动力学 |
| DOI： |
| 分类号:O63 |
| 基金项目: |
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| Kinetic study on the hydrolysis of PNPP catalyzed by dihydroxamic acids open chain crown ether complexes |
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WEI Xing-yue HE Ai-hua WANG Yan-tao LIU Min CHEN Zheng-Chun
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| Abstract: |
| Three dihydroxamic acids open chain crown ether containing central functional group(-OCH3) transition-metal complexes were used as hydrolytic enzyme-mimic model to catalyze carboxylic acid esters(PNPP) hydrolysis.The kinetics and the mechanism of PNPP hyd |
| Key words: central functional group,hydroxamic acids,PNPP hydrolysis,kinetics |
