Under the national conditions of "mass entrepreneurship and innovation", the development of innovation and entrepreneurship has become a research hotspot, but few scholars have studied it from the form of "partnership". By taking the national-level hi-tech enterprises for entrepreneurship and innovation as survey objects, via using Nvivo research tool, based on organizational governance perspective, this paper discusses the partnership mechanism and behavior path for the enterprises with entrepreneurship and innovation under different business situations. The analysis shows that the partnership between individual and individual takes resources complementarity as the core and accomplishes the business process from breeding to double win via camera control mechanism, that the partnership between individual and legal person (organization) takes sustainable complementarity as the core and accomplishes the business process from grownup to double win through time-sharing contingency mechanism and that the partnership between legal person (organization) and legal person (organization) takes middle link as the core and accomplishes the business process from competition to double win through time-sharing contingency mechanism. All above partnership behavior paths can have innovation incentive and realize risk sharing and double win with partnership.