By selecting Shanghai，Anhui and Chongqing as the typical representative of east，middle and west part of China，through industrial structure deviation degree analysis，labor productivity and employment elasticity measurement are used to compare the coordination of industrial structure and employment structure in the three regions and the results show that each region of China has a lot of surplus laborers in the primary industry who are urgently needed to be transferred，that the more balanced the primary industry production and employment structure are in the regions with high urbanization level and industrialization level，the lower their comparative productivity is，that the adsorbing capacity of Shanghai secondary industry on employment is approximate to saturation，however，the secondary industry of Anhui and Chongqing still has big employment adsorbing capacity，that the tertiary industry of Shanghai has limited employment promotion effect，however，the tertiary industry of Anhui and Chongqing has bigger employment potential capacity. Thus，the east part of China must depend on the capacity of science and technology innovation to realize laborers transfer through industrial structure upgrading to further raise the coordination between industrial structure and employment structure while the middle and west part of China should sufficiently take the advantage of labor cost to actively accept industry transfer from the east part to raise the coordination between industrial structure and employment structure.