几种浸出方法重金属浸出浓度与浸提率差异的研究
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The Differences between Leaching Concentrations & Leaching Rates of Heavy Metals with Different Leaching Methods and the Main affecting Factors
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    摘要:

    以某废弃化工厂产生的铬渣,采集的铬污染土壤及配制的铅污染土壤为样品,对比了国内和美国环保几种常见浸出方法的浸出浓度、浸提率并提出相关影响因素;实验结果表明:阳离子(如Cr3+和Pb2+)的浸提率主要受到重金属的存在形态、H+离子的离子交换作用和固态基质的酸蚀这3种因素影响,通常固态基质酸蚀作用影响较大,pH越低,浸出率越高;阴离子(如CrO2-4)的浸提率主要受到OH-离子的离子交换作用和固态基质的酸蚀2种因素影响,通常固态基质的酸蚀影响大于OH-离子的离子交换作用;浸出浓度同时受浸提率和液固比的影响,可能导致出现高浸提率、低浸出浓度的现象。

    Abstract:

    The leaching effects and main affecting factors were investigated for different leaching methods used in China and USA with chromite ore processing residue from an abandoned chemical plant,chromiumcontaminated soil and spiked leadcontaminated soil Results show that for the cations(eg Cr3+and Pb2+),their leaching rates are mainly affected by their occurring forms,ionexchange of H+ and acid etching to solid matrix,and acid etching to solid matrix play the major effects,the lower the pH,the higher the leaching rates For anions(eg CrO2-4),their leaching rates are mainly affected by ionexchange of OH- and acid etching to solid matrix which usually play more significant role than ionexchange effect Furthermore,leaching concentrations are affected by leaching rates and liquidsolid ratio,which might result in high leaching rates with low leaching concentrations

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桂宸鑫, 李东, 胡思扬,袁兴中.几种浸出方法重金属浸出浓度与浸提率差异的研究[J].重庆工商大学学报(自然科学版),2018,35(6):1-6
GUI Chenxin,LI dong*,,HU Siyang,YUAN Xingzhong. The Differences between Leaching Concentrations & Leaching Rates of Heavy Metals with Different Leaching Methods and the Main affecting Factors[J]. Journal of Chongqing Technology and Business University(Natural Science Edition),2018,35(6):1-6

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  • 在线发布日期: 2018-11-19
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